Influence of the pore structure on the catalytic performance of Rh-supported Zr-MOFs in the hydroformylation of olefins

Zirconium-based metal-organic frameworks (Zr-MOFs) of different pore sizes and structure were synthesized and used for the preparation of the Rh-supported catalysts. The catalytic performance was studied in the hydroformylation of olefins to the corresponding aldehydes. A series of n-alk-1-enes of different chain length and bulky olefins with different size was used to study the influence of the pore size and structure. The results show that the Zr-MOF-based catalysts are very active and show high aldehyde selectivity

Efficient duty cycle MAC protocols for dynamic traffic loads in wireless sensor networks

Idle listening is one of the most significant causes of energy consumption in wireless sensor networks (WSNs), and many protocols have been proposed based on duty cycling to reduce this cost. These protocols, either synchronous or asynchronous, are mainly optimized for light traffic loads. A WSN, however, could often experience bursty and high traffic loads, as may happen for example with broadcast or convergecast traffic. In this thesis, I design and evaluate a new synchronous protocol, DW-MAC (Demand Wakeup MAC), and a new asynchronous protocol, RI-MAC (Receiver Initiated MAC), that are both efficient under dynamic traffic loads, including light or heavy loads. I also design and evaluate ADB (Asynchronous Duty-cycle Broadcasting), a new protocol for efficient multihop broadcasting in WSNs using asynchronous duty cycling. DW-MAC introduces a new low-overhead scheduling algorithm that allows nodes to wake up on demand during the Sleep period of an operational cycle and ensures that data transmissions do not collide at their intended receivers; this demand wakeup adaptively increases effective channel capacity as traffic load increases. RI-MAC, instead, uses receiver-initiated transmissions, in which each transmitter passively waits until its intended receiver wakes up and transmits a beacon frame; this technique minimizes the time a sender and its intended receiver occupy the wireless medium to find a rendezvous time for exchanging data. ADB is integrated with RI-MAC to exploit information only available at this layer; rather than treating the data transmission from a node to all of its neighbors as the basic unit of progress for the multihop broadcast. ADB dynamically optimizes the broadcast at the level of transmission to each individual neighbor of a node as the neighbors asynchronously wakeup, avoiding redundant transmissions and transmissions over poor links, and allowing a transmitter to go to sleep as early as possible. In detailed simulation of all three protocols using ns-2, they each substantially outperform earlier competing protocols in terms of reduced energy and latency and increased packet delivery ratio. I also implemented RI-MAC and ADB in a testbed of MICAz motes using TinyOS and further demonstrate the significant performance improvements made over prior protocols

Attribution of satellite-observed vegetation trends in a hyper-arid region of the Heihe River basin, Western China

Terrestrial vegetation dynamics are closely influenced by both climate and by both climate and by land use and/or land cover change (LULCC) caused by human activities. Both can change over time in a monotonic way and it can be difficult to separate the effects of climate change from LULCC on vegetation. Here we attempt to attribute trends in the fractional green vegetation cover to climate variability and to human activity in Ejina Region, a hyper-arid landlocked region in northwest China. This region is dominated by extensive deserts with relatively small areas of irrigation located along the major water courses as is typical throughout much of Central Asia. Variations of fractional vegetation cover from 2000 to 2012 were determined using Moderate Resolution Imaging Spectroradiometer (MODIS) vegetation index data with 250 m spatial resolution over 16-day intervals. We found that the fractional vegetation cover in this hyper-arid region is very low but that the mean growing season vegetation cover has increased from 3.4 % in 2000 to 4.5 % in 2012. The largest contribution to the overall greening was due to changes in green vegetation cover of the extensive desert areas with a smaller contribution due to changes in the area of irrigated land. Comprehensive analysis with different precipitation data sources found that the greening of the desert was associated with increases in regional precipitation. We further report that the area of land irrigated each year can be predicted using the runoff gauged 1 year earlier. Taken together, water availability both from precipitation in the desert and runoff inflow for the irrigation agricultural lands can explain at least 52 % of the total variance in regional vegetation cover from 2000 to 2010. The results demonstrate that it is possible to separate the satellite-observed changes in green vegetation cover into components due to climate and human modifications. Such results inform management on the implications for water allocation between oases in the middle and lower reaches and for water management in the Ejina oasis

Impedance interaction modeling and analysis for bidirectional cascaded converters

© 2015 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.For the cascaded converter system, the output impedance of source converter interacts with the input impedance of load converter, and the interaction may cause the system instability. In bidirectional applications, when the power flow is reversed, the impedance interaction also varies, which brings more uncertainty to the system stability. An investigation is performed here for showing that the forward and reverse interactions are prominently different in terms of dynamics and stability even though the cascaded converter control remains unchanged. An important guideline has been drawn for the control of the cascaded converter. That is when voltage mode converter working as the load converter; the constant power mode converter as the source converter, the system is more stable. The concluded findings have been verified by simulation and experimental results

Impedance coordinative control for cascaded converter in bidirectional application

© 2015 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.Two stage cascaded converters are widely used in bidirectional applications, but the negative impedance may cause system instability. Actually the impedance interaction is much different between forward power flow and reversed power flow, which will introduce more uncertainty to the system stability. This paper proposes a control method for the constant power controlled converter in cascaded system, and consequently it can change the negative impedance of constant power converter into resistive impedance, which will improve the cascaded system stability, as well as merge the impedance difference between forward and reversed power flow. This paper addresses the analysis with the topology of cascaded dual-active-bridge converter (DAB) with inverter, and the proposed control method can also be implemented in unidirectional applications and other general cascaded converter system. The effectiveness has been validated by both simulation and experimental results

Active Power and DC Voltage Coordinative Control for Cascaded DC–AC Converter With Bidirectional Power Application

("(c) 2015 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other users, including reprinting/ republishing this material for advertising or promotional purposes, creating new collective works for resale or redistribution to servers or lists, or reuse of any copyrighted components of this work in other worksTwo stage-cascaded converters are widely used in dc–ac hybrid systems to achieve the bidirectional power transmission. The topology of dual active bridge cascaded with inverter DABCI) is commonly used in this application. This paper proposes a coordinative control method for DABCI and it is able to reduce the dc-link voltage fluctuation between the DAB and inverter, then reduce the stress on the switching devices, as well as improve the system dynamic performance. In the proposed control method, the DAB and inverter are coordinated to control the dc-link voltage and the power, and this responsibility sharing control can effectively suppress the impact of the power variation on the dc-link voltage, without sacrificing stability. The proposed control method is also effective for DABCI in unidirectional power transmission. The effectiveness of the propose control has been validated by both simulations and experiments

Energy Efficient Indirect Evaporative Air Cooling

An energy-saving and environmentally friendly air-conditioning method has been proposed. The key component is a novel indirect evaporative heat exchanger (IEHX) based on the M-cycle. In this design, the compact IEHX is able to produce sub-wet-bulb cooling and reduce the air temperature approaching dew-point temperature. This chapter aims to achieve a fundamental understanding of the novel IEHX. A numerical model has been developed and validated by comparing the simulated outlet air conditions against experimental data. The model showed a good agreement with the experimental findings. Employing the validated numerical model, we have theoretically investigated the heat and mass transfer behavior occurred in the IEHX. The detailed cooling process has been analyzed on the psychrometric chart. In addition, the effects of varying inlet conditions and airflow passage dimensions on the cooling efficiency have been studied. By analyzing the thermal performance of the IEHX, we have provided possible suggestions to improve the performance of the dew-point cooler and enable it to attain higher cooling effectiveness

Characterization of severe fever with thrombocytopenia syndrome in rural regions of Zhejiang, China.

Severe fever with thrombocytopenia syndrome virus (SFTSV) infections have recently been found in rural regions of Zhejiang. A severe fever with thrombocytopenia syndrome (SFTS) surveillance and sero-epidemiological investigation was conducted in the districts with outbreaks. During the study period of 2011-2014, a total of 51 SFTSV infection cases were identified and the case fatality rate was 12% (6/51). Ninety two percent of the patients (47/51) were over 50 years of age, and 63% (32/51) of laboratory confirmed cases occurred from May to July. Nine percent (11/120) of the serum samples from local healthy people without symptoms were found to be positive for antibodies to the SFTS virus. SFTSV strains were isolated by culture using Vero, and the whole genomic sequences of two SFTSV strains (01 and Zhao) were sequenced and submitted to the GenBank. Homology analysis showed that the similarity of the target nucleocapsid gene from the SFTSV strains from different geographic areas was 94.2-100%. From the constructed phylogenetic tree, it was found that all the SFTSV strains diverged into two main clusters. Only the SFTSV strains from the Zhejiang (Daishan) region of China and the Yamaguchi, Miyazakj regions of Japan, were clustered into lineage II, consistent with both of these regions being isolated areas with similar geographic features. Two out of eight predicted linear B cell epitopes from the nucleocapsid protein showed mutations between the SFTSV strains of different clusters, but did not contribute to the binding ability of the specific SFTSV antibodies. This study confirmed that SFTSV has been circulating naturally and can cause a seasonal prevalence in Daishan, China. The results also suggest that the molecular characteristics of SFTSV are associated with the geographic region and all SFTSV strains can be divided into two genotypes